[1H-1,2,4-Triazole-5(4H)-thione-κS]bis(triphenylphosphane-κP)(nitrato-κO)silver(I) methanol monosolvate
نویسندگان
چکیده
In the title complex, [Ag(NO3)(C2H3N3S)(C18H15P)2]·CH3OH, the Ag(I) ion exhibits a distorted tetra-hedral coordination geometry formed by two P atoms from two tri-phenyl-phosphine ligands, one S atom from a 1H-1,2,4-triazole-5(4H)-thione ligand and one O atom from a nitrate ion. In the crystal, complex and solvent mol-ecules are linked by O-H⋯O and N-H⋯O hydrogen bonds forming a chain along the b-axis direction. The chains are linked by weak C-H⋯O hydrogen bonds forming a two-dimensional supra-molecular architecture parallel to (001). In addition, an intra-molecular N-H⋯O hydrogen bond is observed.
منابع مشابه
Chlorido[1H-1,2,4-triazole-5(4H)-thione-κS]bis(triphenylphosphane-κP)copper(I) acetronitrile monosolvate
In the title solvate, [CuCl(C2H3N3S)(C18H15P)2]·CH3CN, the Cu(I) ion is bonded to two triphenyl-phosphane ligands, one 1H-1,2,4-triazole-5(4H)-thione ligand via its S atom and one chloride ion in a distorted CuP2SCl tetra-hedron. An intra-molecular N-H⋯Cl hydrogen bond, which closes an S(6) ring, helps to establish the conformation of the complex. In the crystal, N-H⋯Cl hydrogen bonds and C-H⋯π...
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